Non-isothermal Crystallization of Polymers

This paper is devoted to the study of mathematical problems arising in the modelling of nonisothermal polymer crystallization under industrial conditions. A review of the hybrid stochastic-deterministic modelling procedure, which yields an averaged model 5;8 , is given and supplied by the study of mathematical problems arising from it. Furthermore, multiple scale eeects in the crystallization process are studied using diierent scalings, focussing either on the heat conduction or on the crystallization part. It is shown that in the limit of fast nucleation and slow growth, the model is equivalent to a direct extension of the classical Avrami-Kolmogorov model equations. In addition, numerical simulations are presented to illustrate the behaviour during crystallization. Finally, open questions from mathematical and engineering view points are discussed.